Abstract
This paper will review a new technique of detecting companion stars in LMXBs and X-ray transients in outburst using the Bowen fluorescence NIII lines at 4634-4640. These lines are very efficiently reprocessed in the atmospheres of the companion stars and, thereby, provide estimates of the K[2] velocities and mass functions. The method has been applied to Sco X-1, X1822-371 and GX339-4 which, in the latter case, provides dynamical evidence for the presence of an accreting black hole. Preliminary results from a VLT campaign on V801 Ara, V926 Sco and XTE J1814-338 are also presented.